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Variacion de la resistencia de compresin, una idea en teoría. Abstract. This article presents a model for the variation of the compressive modulus with temperature based on the well-established theory of the thermally activated hopping process in glass formers.

The present model successfully describes the variation of the ratio of the elastic moduli of the glass and the polymer with temperature. It predicts qualitatively correct and quantitative results with increasing number of activated modes.

The model is applied to styrene-butadiene copolymer (SBR) and is compared to experimental data obtained from modulus measurements of SBR and glassy polymers, in a two-stage system, that is, from the glassy polymer to the plastic and the dynamic viscoelasticity.

The relative maximum of the compliance (the slope) of the SBR increases with increasing temperature from 22% at – 20 °C to 26% at 40 °C.

The maximum of the sensitivity (the ratio of the slope of the compliance to the compliance itself) of the SBR increases with increasing temperature from 24 at – 20 °C to 30 at 40 °C.

The sensitivity of the SBR to temperature lies within the region of transition.

CONDENSATES OF GLASS FORMERS: polymers, copolymers, and composites

Glass-forming systems represent a rich variety of structural materials, from polymers to minerals, and from ores to ceramic composites. Although polymers represent the largest segment of glass-forming materials, the composites category includes those materials that are representative of structures like semiconductor components, pharmaceutical products, or prosthetic devices. Glass-forming systems form via either nucleation or homogeneous nucleation events. The glass-forming systems that follow nucleation are the polymers, the copolymers, and the simple or complex composites.

Polymer

The polymer is defined as a large molecule that is characterized by the presence of repeating structures (monomer units). Polymers form via the nucleation and growth of gel crystals inside a polymer matrix.

Thermal analysis of glass-forming polymers can be useful to understand
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